Oct 19, 2019   7:10 p.m. Kristián
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Course syllabus N413P0_4I - Industrial Organic Chemistry (FCFT - WS 2019/2020)

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University: Slovak University of Technology in Bratislava
Faculty: Faculty of Chemical and Food Technology
Course unit code: N413P0_4I
Course unit title: Industrial Organic Chemistry
Mode of completion and Number of ECTS credits: Exam (4 credits)
Course contents:
1.Products from methane (allowance 2/2)
a.Production of synthesis gas - steam reforming, partial oxidation
b.Chemicals from synthesis gas - ammonia, urea, methanol
c.Chemicals from methanol - formaldehyde, acetic acid, acetic anhydride, methylamine, dimethyl carbonate, a.o. and their utilisation
d.Production and uses of hydrocyanid acid
e.Production of acetylene - the most important chemicals based on acetylene
f.The Fischer -Tropsch reaction
g.Hydroformylation of olefines

2.Products from ethylene (allowance 2/2)
a.Production and uses of ethylene polymers and copolymers
b.Production and uses of ethylene oligomers - dimerization, Ziegler oligomerization of ethylene, SHOP
c.Production and uses of oxidation products - acetaldehyde, vinyl acetate, vinyl chloride, ethylene oxide
d.Production and uses of styrene
e.Production and uses of alcohols
f.Ethylene from renewables

3.Products from propylene (allowance 1/1)
a.Production and uses of propylene polymers, copolymers and oligomers
b.Production and uses of oxidation products - acroleine, acrylic acid, acrylonitrile, propylene oxide
c.Production and uses of cumene
d.Production and uses of n-butyraldehyde and isobutyraldehyde
e.Production and uses of methacrylic acid and methyl methacrylate
f.Production and uses of propylene glycoles
g.Epichlorhydrine from classical process and epicerol based on bioglycerol
h.Comparing the preparation method of 1,2-propanediol and 1,3-propanediol based on petroleum and biogycerol

4.Chemicals and polymers from C4 stream (allowance 1/1)
a.Production and uses of chemicals from butadiene - main elastomers, ABS resin
b.Production and uses of hexamethylenediamine
c.Lesser volume chemicals from butadiene - cyclization, dimerization and trimerization, Diels-Alder Reactions, adipic acid, dimethyl-2,6-naphthalene dicarboxylate, butadiene monoepoxide
d.Production and uses of chemicals and polymers from isobutene - methyl tert-butyl ether, butyl rubber, polyisobutenes and isobutene oligomers and polymers, tert-butanol, lesser volume chemicals from isobutene - 2,6-ditert-butyl-4-methylphenol, tert-butyl-4-hydroxyanizole
e.Production and uses of chemicals and polymers from 1- and 2-butenes
f.Production and uses of chemicals from n-butane - acetic acid, maleic anhydride

5.Chemicals and polymers from C5 stream (allowance 1/1)
a.Major components, sources and separation of the C5 stream
b.Uses of isoprene
c.Uses of cyclopentadiene and dicyclopentadiene
d.Uses of pentene-1 and piperylene

6.Chemicals and polymers from benzene (allowance 3/3)
a.Production and uses of phenol - phenolic resin, bisphenol A, epoxy resins, polycarbonate resins, cyclohexanone, alkylphenols, salicylic acid, parabenes
b.Production and uses of cyclohexane - adipic acid, polyamid66, caprolactam, polyamide6
Comparison of the conventional method of caprolactame preparation with the new, environmentally more frendly process
c.Production and uses of aniline - 4,4'-diphenylmethane diisocyanate
d.Production and uses of alkylbenzenes - cumene, linear higher alkylbenzenes (C10-14)
e.Production and uses of maleic anhydride - comparion the ecology of their methods of production
f.Production and uses of dihydroxybenzene
g.Production and uses of antraquinone

7.Chemicals and polymers from toluene (allowance 1/1)
a.Hydrodealylation and disproportionation
b.Dinitrotoluene and toluene diisoyanete
c.Lesser volume chemicals from toluene - phenol, caprolactam, benzyl chloride, benzaldehyde, benzyl alkohol, benzoic acid, styrene

8.Chemicals and polymers from xylenes (allowance 1/1)
a.Production and utilization of o-xylene and phthalic anhydride
b.Production and utilization of m-xylene and isophthalic acid
c.Production and utilization of p-xylene - terephthalic acid and dimethyl terephthalate
d.Alternate sources for terephthalic acid
e.Production and utilization of poly(ethylene terephthalate), poly(butylene terephthalate), poly(trimethylene terephthalate)
f.Aramides - Kevlar, Nomex

9.Renewable carbon sources (allowance 1/1)
a.Types of renewable carbon sources - weaknesses of renewable raw materials
b.Wood -- uses, chemical commodities produced from wood, the chemical composition of wood pulp, chemical transformations in the processing of wood, by-products, uses of noble pulp
c.Fats and oils - chemical processing of fats, fatty acid esters, metal soaps, fatty amines, fatty acid amides, hydrogenation of fatty acids and amines
d.Conversion of biomass to fuels - "green diesel", advantages in comparison with FAME, hydrolysis methods and subsequent conversion of biomass to fuels, enzymatic hydrolysis of biomass, pyrolytic processes for conversion of biomass to fuels

Last modification made by Ing. Tomáš Molnár on 01/29/2019.

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