Sep 20, 2019   5:11 a.m. Ľuboslav, Ľuboslava
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Course syllabus 414C1_4I - Organometallic Compounds (FCFT - SS 2019/2020)


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University: Slovak University of Technology in Bratislava
Faculty: Faculty of Chemical and Food Technology
Course unit code: 414C1_4I
Course unit title: Organometallic Compounds
Mode of delivery, planned learning activities and teaching methods:
lecture2 hours weekly (on-site method)
seminar1 hour weekly (on-site method)

 
Credits allocated: 4
 
Recommended semester/trimester: Technical Chemistry - master (optional), 2. semester
Level of study: 2.
Prerequisites for registration: none
 
Assesment methods:
The exam consists of a written test and an oral test for 50 points. To successfully passing the exam, the student must achieve at least 28 points.
Students are graded as follows: A 46-50 points, B 41-45 points, C 37-40 points, D 32-36 points, E 28-31 points.
 
Learning outcomes of the course unit:
Knowlege of chemistry of organometallic compounds and their applications in the organic synthesis.
 
Course contents:
Introduction to organometallic chemistry : definition and classification (on basis of ligand type), formalisms, oxidation state, coordination state, example of carbine and carbyne complexes. Hapticity, structure, bonding and reactivity in ethylenic and allylic complexes. Synthesis, structure, bonding and reactivity in carbene and carbyne complexes, fluxional behaviour.
Reaction mechanism: preliminary ideas on different types of mechanisms (oxidative addition, reductive elimination, insertion, -H elimination, transmetallation, attack on ligand), an idea on trans effect. Reductions of the unsaturated bond (Wilkinson, Crabtree. "Cross coupling" reactions (Karash, Suzuki, Sonogashira, Stille, Kumada, Negishi, Heck). Alkene-/alkyne metatheses (Schrock, Grubbs, Hoveyda). Carbonylations and oxycarbonylations. Total syntheses.
 
Recommended or required reading:
Basic:
HEGEDUS, L. Organische Synthese mit Ubergangsmetallen. Weinheim-New York-Basel-Cambridge-Tokyo: VCH Publishers, Inc., 1995. ISBN 3-527-29255-1.
SALZER, A. -- ELSCHENBROICH, C. Organometallics. Weinheim-New York-Basel-Cambridge-Tokyo: VCH Publishers, Inc., 1992. ISBN 3-527-28164-9.
PFALTZ, A. -- YAMAMOTO, H. -- JACOBSSEN, E. Comprehensive Asymmetric Catalysis. Berlin- Heidelberg-New York : Springer-Verlag, 1999. ISBN 3-540-64336-2.

 
Language of instruction: -- item not defined --
 
Notes:
 
Courses evaluation:
Assessed students in total: 124

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Name of lecturer(s): prof. Ing. Tibor Gracza, DrSc. (person responsible for course) - slovak
 
Last modification: 29. 1. 2019
Supervisor: prof. Ing. Tibor Gracza, DrSc. and programme supervisor


Last modification made by Ing. Tomáš Molnár on 01/29/2019.

Type of output: