Magneto-structural relationships for novel substances and materials.Supervisor: prof. Ing. Roman Boča, DrSc.
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|Project description:||As a result of our joint venture between the TU Darmstadt and STU Bratislava we synthesized new substances with interesting magnetic properties. The X-ray structure analysis revealed the composition and the structural motif of the complexes. The magnetic data were taken with the SQUID magnetometer in two regimes: the temperature dependence of the magnetic susceptibility, and the field dependence of the magnetization at low temperature. The data were analyzed with own unique software. Of our central interests are: (i) magnetic anisotropy predominantly in nickel(II) complexes which manifest itself in a large zero-field splitting; (ii) the spin crossover phenomenon in iron(II) complexes with a possible hysteresis and consequently memory effect; (iii) structural and magneto-structural correlations.|
|Kind of project:||Dohoda STU ()|
|Department:||Department of Inorganic Chemistry (IICTM FCFT)|
|Project status:||Successfully completed|
|Project start date :||01. 01. 2005|
|Project close date:||31. 12. 2008|
|Number of workers in the project:||2|
|Number of official workers in the project:||0|